How to display a list of items when some have already been used

Our application has a security section which provides a list of users from AD and roles to be added for access to the program. Once a user is added, I'm not sure how best to display or not display that user again when this security section is accessed again and more users are added. I see 3 options:

  1. Do not show a user once they have been added.
  2. Disable the user in the AD list if they have already been added.
  3. Do nothing. This would appear that the user can be added and I would allow the process to continue but nothing is really being added since the user already exists.

There will be other similar actions within the program. Has anyone run into a similar situation?

The form will look something like this. Users are selected from the left and roles selected from the right. Save adds the user/roles combinations to the database. Once a user/role has been added, there's really no need to go back to this window to do anything with a user who has already been added. enter image description here